A face-capped [Fe4L4]8+ spin crossover tetrahedral cage.

نویسندگان

  • Alan Ferguson
  • Marie A Squire
  • Diana Siretanu
  • Dmitri Mitcov
  • Corine Mathonière
  • Rodolphe Clérac
  • Paul E Kruger
چکیده

Reported here is a face-capped Fe(ii) molecular tetrahedron, [Fe(4)L(4)](BF(4))(8), . Single crystal X-ray diffraction at 153 and 293 K suggest spin crossover (SCO) and variable temperature magnetic susceptibility measurements confirm displays thermally driven SCO behaviour in the solid state and in dilute acetone solution centred around 284-288 K.

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عنوان ژورنال:
  • Chemical communications

دوره 49 16  شماره 

صفحات  -

تاریخ انتشار 2013